Chemical Safety Information

Safe use, storage and transportation of chemicals is essential for any facility.

Proper safe handling of chemicals by employees and safe chemical operations will prevent accidents, chemical exposures and chemical release to the environment. The Safety Library contains a large volume of chemical safety information to assist you in all aspects of your programs from Process Safety Management to proper chemical storage and Material Safety Data Sheet use, as well as selection of the proper chemical personal protection equipment to protect your employees from chemical exposure.

Hazard Communication (HazCom)

In order to ensure chemical safety in the workplace, information must be available about the identities and hazards of the chemicals. OSHA's Hazard Communication Standard (HCS) requires the development and dissemination of such information:

Chemical manufacturers and importers are required to evaluate the hazards of the chemicals they produce or import, and

Prepare labels and material safety data sheets (SDSs) to convey the hazard information to their downstream customers.

All employers with hazardous chemicals in their workplaces must have labels and SDSs for their exposed workers, and train them to handle the chemicals appropriately.

Written Hazard Communication Program

A written hazard communication program ensures that all employers receive the information they need to inform and train their employees properly and to design and put in place employee protection programs. It also provides necessary hazard information to employees, so they can participate in, and support, the protective measures in place at their workplaces. Employers therefore must develop, implement, and maintain at the workplace a written, comprehensive hazard communication program that includes provisions for container labeling, collection and availability of material safety data sheets, and an employee training program. It also must contain a list of the hazardous chemicals, the means the employer will use to inform employees of the hazards of non-routine tasks (for example, the cleaning of reactor vessels), and the hazards associated with chemicals in unlabeled pipes. If the workplace has multiple employers onsite (for example, a construction site), the rule requires these employers to ensure that information regarding hazards and protective measures be made available to the other employers onsite, where appropriate. In addition, all covered employers must have a written hazard communication program to get hazard information to their employees through labels on containers, SDSs, and training.

The written program does not have to be lengthy or complicated, and some employers may be able to rely on existing hazard communication programs to comply with the above requirements. The written program must be available to employees, their designated representatives, OSHA and NIOSH.

SDS Information - Safety Data Sheets

A Safety Data Sheet, often referred to by its acronym SDS, is a detailed informational document prepared by the manufacturer or importer of a hazardous chemical which describes the physical and chemical properties of the product. Information included in a Safety Data Sheet aids in the selection of safe products, helps employers and employees understand the potential health and physical hazards of a chemical and describes how to respond effectively to exposure situations.ting.

The format of a Safety Data Sheet may vary but there is specific information that must be included in each sheet. It is useful to review this information to increase your ability to use a Safety Data Sheet.

All Safety Data Sheets should include the following information:
• Section 1: Chemical Product & Company Information - Provides the chemical name on the label to the SDS. Also listed is the name, address and the phone number of the company, manufacturer or distributor who provides the chemical.
• Section 2: Composition & Ingredients - Identifies all hazardous ingredients, OSHA permissible exposure limits (PEL) & ACGIH (American Conference of Governmental Industrial Hygienists) Threshold Limit Values (TLVs).
• Section 3: Hazard Identification - Information about the health effects of exposure. Description of the appearance, potential symptoms & health effects, routes of entry & target organs.
• Section 4: First Aid - Provides first aid procedures for each route of entry.
• Section 5: Fire-Fighting - Information on the explosive & fire properties, extinguishing agents and items and general fire-fighting information.
• Section 6: Accidental Release - Information on spill response, containment and required spill response PPE.
• Section 7: Handling and Storage - Information about chemical storage & handling and measures to prevent over-exposure.
• Section 8: Exposure Controls & Personal Protection - Engineering controls & personal protective equipment to reduce chemical exposure.
• Section 9: Physical & Chemical Properties - This section tells about the physical and chemical properties of the chemical. Characteristics include appearance, odor, physical state, pH, vapor pressure, vapor density, boiling point, freezing/melting point, solubility in water and specific gravity or density.
• Section 10: Stability & Reactivity - All potentially hazardous chemical reactions are identified in this section. Includes information on chemical stability, conditions to avoid, incompatibility, hazardous decomposition and hazardous polymerization.
• Section 11: Toxicological Information - Provides information such as acute data, carcinogen potential, reproductive effects, target organ effects, and other physiological aspects
• Section 12: Ecological Information - Information concerning the environmental impact if a chemical is released into the environment.
• Section 13: Disposal Considerations - Information concerning proper chemical disposal, recycling and reclamation.
• Section 14: Transport Information - Shipping information includes the hazardous s description, hazard class and the identification number (UN or NA numbers).
• Section 15: Regulatory Information - Provides information about applicable federal regulations. Examples include OSHA, TSCA (Toxic Substance Control Act), CERCLA (Comprehensive Environmental Response, Compensation, and Liability Act), SARA Title III (Superfund Amendments and Reauthorization Act).
• Section 16: Additional Information - Provides other information about the chemical such as hazard ratings, preparation and revisions of the SDS, and label information.g.

All materials in the members area for this topic index

Program Material

Programs (written)
(7)
 Benzene ChemicalDownloadMS-WORD
 Dry Ice Solid Carbon Dioxide Safety ProgramDownloadMS-WORD
 Formaldehyde Safety ProgramDownloadMS-WORD
 Hazard Communication And Chemical Safety ProgramDownloadMS-WORD
 Laboratory Chemical Safety And Hygiene Program Safety ProgramDownloadMS-WORD
 Lead Safety General Industry Safety ProgramDownloadMS-WORD
 Metalworking Fluids Best Practices Manual Safety ProgramDownloadMS-WORD
Program Development
(3)
 Chemical StorageDownloadMS-WORD
 Hazard Communication Program DevelopmentDownloadMS-WORD
 SDS Material Safety Data Sheet Program DevelopmentDownloadMS-WORD
Fact Sheets
(25)
 Benzene Safety Topic Fact SheetDownloadMS-WORD
 Broken Fluorescent Bulb Cleanup Safety Topic Fact SheetDownloadMS-WORD
 Chemical CarcinognesDownloadMS-WORD
 Chemical Control Banding Safety Topic Fact SheetDownloadMS-WORD
 Chemical Cpc EvaluationDownloadMS-WORD
 Chemical GlossaryDownloadMS-WORD
 Chemical Gloves Safety Topic Fact SheetDownloadMS-WORD
 Chemical GlovesDownloadMS-WORD
 Chemical Idlh MainDownloadMS-WORD
 Chemical IncompatibleDownloadMS-WORD
 Chemical Label HmisDownloadMS-WORD
 Chemical Labels Hmis Safety Topic Fact SheetDownloadMS-WORD
 Chemical Labels Nfpa Safety Topic Fact SheetDownloadMS-WORD
 Chemical ReactiveDownloadMS-WORD
 Chemical SDS InfoDownloadMS-WORD
 Chemical StorageDownloadMS-WORD
 Chemical ToxicologyDownloadMS-WORD
 Dry Ice Safety Topic Fact SheetDownloadMS-WORD
 Hazard Communication Safety Topic Fact SheetDownloadMS-WORD
 Lab Chemical Safety Topic Fact SheetDownloadMS-WORD
 Manual Globally Harmonized System Of Classification And Labeling Of Chemicals Safety Topic Fact SheetDownloadMS-WORD
 Methylene Chloride Safety Topic Fact SheetDownloadMS-WORD
 Naerg Instructors Guide Safety Topic Fact SheetDownloadMS-WORD
 SDS Safety Topic Fact SheetDownloadMS-WORD
 Terrorism Hsd Chemical Facility Security RegDownloadMS-WORD

Forms & Documents

Audits
(1)
 Chemical Safety Audit GuideDownloadMS-WORD
Checklists
(1)
 Chemical Safety Supervisor Safety ChecklistDownloadMS-WORD
Forms
(6)
 Chemical Inventory List FormDownloadMS-WORD
 Employee Chemical Exposure Report FormDownloadMS-WORD
 Hazcom Training Certificate FormDownloadMS-WORD
 Hot Work Permit FormDownloadMS-WORD
 SDS Material Safety Data Sheet FormDownloadMS-WORD
 SDS Request Letter FormDownloadMS-WORD
Inspections
(3)
 Hazard Communication Inspection General FormDownloadMS-WORD
 Hazardous Chemicals Inspection General FormDownloadMS-WORD
 Pool Chemical Use and Storage SafetyDownloadMS-WORD

Training Material

Accident Reports
(11)
 Chemical Release AccidentDownloadMS-WORD
 Freon Sends 2 To Hospital AccidentDownloadMS-WORD
 Hydrochloric Acid Spill AccidentDownloadMS-WORD
 Lightning Sparks Chemical Fire AccidentDownloadMS-WORD
 Piping System AccidentDownloadMS-WORD
 Plastics Plant Explosion AccidentDownloadMS-WORD
 Propane Explosion AccidentDownloadMS-WORD
 Propane Leak AccidentDownloadMS-WORD
 Sulfur Dioxide Release AccidentDownloadMS-WORD
 Water Reactive Chemical AccidentDownloadMS-WORD
 Welding 01 AccidentDownloadMS-WORD
Articles
(2)
 Hydraulics Safety ArticleDownloadMS-WORD
 Skin Chemical Exposure Safety ArticleDownloadMS-WORD
Crossword Puzzle
(2)
 Chemical Crossword Answer KeyDownloadMS-WORD
 Chemical CrosswordDownloadMS-WORD
Guides
(19)
 Chemical A BasicsDownloadMS-WORD
 Chemical AcidsDownloadMS-WORD
 Chemical AdhesivesDownloadMS-WORD
 Chemical BasesDownloadMS-WORD
 Chemical Cleaning CompoundsDownloadMS-WORD
 Chemical Comp GasDownloadMS-WORD
 Chemical Corr Prev CmpdsDownloadMS-WORD
 Chemical DetergentDownloadMS-WORD
 Chemical FuelsDownloadMS-WORD
 Chemical GreasesDownloadMS-WORD
 Chemical Heavy MetalDownloadMS-WORD
 Chemical HydraulicDownloadMS-WORD
 Chemical Inspect PenetrantsDownloadMS-WORD
 Chemical LubricantsDownloadMS-WORD
 Chemical OxidizersDownloadMS-WORD
 Chemical PaintDownloadMS-WORD
 Chemical PolishDownloadMS-WORD
 Chemical SolventsDownloadMS-WORD
 Chemical Water Treatment ChemDownloadMS-WORD
Handouts
(10)
 Chemical Hazcom2012 Employee Training Hazcom 2012 Training HandoutDownloadMS-WORD
 Chemical Hazcom2012 GHS English Pictograms And Hazards KoreanDownloadMS-WORD
 Chemical Hazcom2012 GHS English Pictograms And HazardsDownloadMS-WORD
 Chemical Hazcom2012 GHS Spanish Pictograms And HazardsDownloadMS-WORD
 Chemical Hazcom2012 HCS GHS Chemical Hazard ClassificationsDownloadMS-WORD
 Chemical Training Handout SpanishDownloadMS-WORD
 Chemical Training HandoutDownloadMS-WORD
 GHS Training Handout KoreanDownloadMS-WORD
 Leak Response Training HandoutDownloadMS-WORD
 SDS Training HandoutDownloadMS-WORD
Management
(5)
 Chemical Hazcom2012 Management Brief 2012 Hazcom GHSDownloadMS-WORD
 Chemical Screening Chem Reactive HazardsDownloadMS-WORD
 Contact Lenses In Chemical Environments Management Safety BriefDownloadMS-WORD
 Hazard Communication Management Safety BriefDownloadMS-WORD
 Management 2012 Changes To The OSHA Hazard Communication StandardDownloadMS-WORD
Outlines
(1)
 Hazard Communication Training OutlineDownloadMS-WORD
Pamphlets
(3)
 Chemical Pamphlet SpanishDownloadMS-WORD
 Chemical Safety PamphletDownloadMS-WORD
 SDS Information PamphletDownloadMS-WORD
PowerPoints
(20)
 40 Hour HAZWOPER PowerPoint SpanishDownloadMS-PPT
 40 hour HAZWOPER PowerPointDownloadMS-PPT
 Benzene PowerPointDownloadMS-PPT
 Cancer and the Workplace PowerPoint SpanishDownloadMS-PPT
 Cancer and the Workplace PowerPointDownloadMS-PPT
 HAZWOPER 8Hr Operations PowerPoint SpanishDownloadMS-PPT
 HAZWOPER 8Hr Operations PowerPointDownloadMS-PPT
 HazCom 10 HourDownloadMS-PPT
 Hazard Communication Chemical 2012 Globally Harmonized System Overview PowerPointDownloadMS-PPT
 Hazard Communication and Chemical Safety PowerPoint SpanishDownloadMS-PPT
 Hazard Communication and Chemical Safety PowerPointDownloadMS-PPT
 Hazardous Waste Management Training PowerPoint SpanishDownloadMS-PPT
 Hazardous Waste Management Training PowerPointDownloadMS-PPT
 Hexavalent Chromium PowerPointDownloadMS-PPT
 Implementation of the Globally Harmonized System GHS Chemical PowerPointDownloadMS-PPT
 Laboratory Chemical Safety PowerPointDownloadMS-PPT
 OSHA Hazard Communication Chemical Employee Training 2012 Changes PowerPointDownloadMS-PPT
 OSHA Hazard Communication for Safety Managers Chemical 2012 PowerPointDownloadMS-PPT
 Process Safety Management Overview PowerPointDownloadMS-PPT
 Working with Chemical Solvents PowerPointDownloadMS-PPT
Quizzes
(3)
 Chemical Hazcom2012 Employee Training Quiz 2012 HCS ChangesDownloadMS-WORD
 Chemical Safety Quiz Answer KeyDownloadMS-WORD
 Chemical Safety QuizDownloadMS-WORD
Reminders/Overheads
(26)
 Chemical Hazards ReminderDownloadMS-WORD
 Chemical Info ReminderDownloadMS-WORD
 Chemical Protection ReminderDownloadMS-WORD
 Chemical Rules ReminderDownloadMS-WORD
 Chemical SDS 01 ReminderDownloadMS-WORD
 Chemical SDS 02 ReminderDownloadMS-WORD
 Chemical SDS 03 ReminderDownloadMS-WORD
 Chemical SDS 04 ReminderDownloadMS-WORD
 Chemical SDS 05 ReminderDownloadMS-WORD
 Chemical SDS 06 ReminderDownloadMS-WORD
 Chemical SDS 07 ReminderDownloadMS-WORD
 Chemical SDS 08 ReminderDownloadMS-WORD
 Chemical SDS 09 ReminderDownloadMS-WORD
 Chemical SDS 10 ReminderDownloadMS-WORD
 Chemical SDS 11 ReminderDownloadMS-WORD
 Chemical SDS 12 ReminderDownloadMS-WORD
 Chemical SDS 13 ReminderDownloadMS-WORD
 Chemical SDS 14 ReminderDownloadMS-WORD
 Chemical SDS 15 ReminderDownloadMS-WORD
 Chemical SDS 16 ReminderDownloadMS-WORD
 Chemicals Hazards ReminderDownloadMS-WORD
 Chemicals Info ReminderDownloadMS-WORD
 Chemicals Protection ReminderDownloadMS-WORD
 Chemicals Rules ReminderDownloadMS-WORD
 Office Chemical ReminderDownloadMS-WORD
 Office P Chemicals ReminderDownloadMS-WORD
Sessions
(1)
 Chemical Safety SessionDownloadMS-WORD
Supervisor
(5)
 2 Minute Safety Gasoline SafetyDownloadMS-WORD
 2brief ChemicalsDownloadMS-WORD
 2brief SDSDownloadMS-WORD
 Chemical Hazcom2012 Brief English Hazard Communication (GHS) Safety Data SheetsDownloadMS-WORD
 Chemical Hazcom2012 Brief Spanish Hazard Communication (GHS) Safety Data SheetsDownloadMS-WORD
Talks
(22)
 Chemical Bonding Grounding Talk SpanishDownloadMS-WORD
 Chemical Bonding Grounding TalkDownloadMS-WORD
 Chemical Chlorine Talk SpanishDownloadMS-WORD
 Chemical Chlorine TalkDownloadMS-WORD
 Chemical Flam Liquids Talk SpanishDownloadMS-WORD
 Chemical Flam Liquids TalkDownloadMS-WORD
 Chemical Hazcom Talk SpanishDownloadMS-WORD
 Chemical Hazcom TalkDownloadMS-WORD
 Chemical Label NFPA TalkDownloadMS-WORD
 Chemical Labels Talk SpanishDownloadMS-WORD
 Chemical Labels TalkDownloadMS-WORD
 Chemical Lead Talk SpanishDownloadMS-WORD
 Chemical Lead TalkDownloadMS-WORD
 Chemical Propane Talk SpanishDownloadMS-WORD
 Chemical Propane TalkDownloadMS-WORD
 Chemical Safety Talk SpanishDownloadMS-WORD
 Chemical Safety TalkDownloadMS-WORD
 Chemical Talk SpanishDownloadMS-WORD
 Chemical TalkDownloadMS-WORD
 Chemical Toxicology Talk SpanishDownloadMS-WORD
 Chemical Toxicology TalkDownloadMS-WORD
 Opps Haz Waste Disposal TalkDownloadMS-WORD
Videos
(8)
 Chemical CorrosiveDownloadOnLine
 Chemical EnvironmentDownloadOnLine
 Chemical FlammableDownloadOnLine
 Chemical HarmfullDownloadOnLine
 Chemical IrritantDownloadOnLine
 Chemical RiskDownloadOnLine
 Chemical ToxicDownloadOnLine
 Reactive Chemical HazardsDownloadOnLine

Awareness

Posters
(16)
 Labels Signs CautionDownloadMS-WORD
 Labels Signs ChmsDownloadMS-WORD
 Labels Signs DangerDownloadMS-WORD
 Labels Signs Exit EmergDownloadMS-WORD
 Labels Signs Exit LeftDownloadMS-WORD
 Labels Signs Exit NotDownloadMS-WORD
 Labels Signs Exit RightDownloadMS-WORD
 Labels Signs ExitDownloadMS-WORD
 Labels Signs NFPDownloadMS-WORD
 Labels Signs NoticeDownloadMS-WORD
 Labels Signs Smoking NoDownloadMS-WORD
 Labels Signs WarningDownloadMS-WORD
 Poster ChemDownloadMS-WORD
 Poster SDS PosterDownloadMS-WORD
 Poster SDSDownloadMS-WORD
 Poster Waste HazardsDownloadMS-WORD
Safety Comic Strip
(1)
 Comic Archive Chemical Mixing Safety Comic StripDownloadMS-WORD

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Topic Index

Accident Prevention
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Slips, Trips & Fall
Training
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Violence Programs
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Training Videos

Back Safety
Chemical Corrosive
Chemical Environmental
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Chemical Harmful
Chemical Irritant
Chemical Risk
Chemical Toxic
Confined Space Death
Confined Space Hazards & Response
Driving & Medication
Drowsy Driving
Electrical Arc Flash Hazards
Emergency Planning
Ergonomics
Eye Protection
Fall Prevention
Fall Protection - Tie Off
Forklift Carbon Monoxide Hazard
Forklift Tipover Accidents
Forklifts & Pedestrians
Healthcare Worker Safety
Hearing Conservation
Hot Work Dangers
Ladder Safety
Lockout - Tagout
Office Safety
Reactive Chemical Hazards - Process
Safety
Safety For Small Business
Substance Abuse
Trenching Basics
Understanding Job Stress - for Managers
Young Worker Safety


Library Index

Training Materials

Videos/Courses
Talks
Articles
PowerPoint
Handouts
Training Overheads
Quizzes
Supervisor Briefs
Management Briefs
Safety Sessions
2 Minute OSHA Safety Talks
Pamphlets
First Aid Training
Supervisor Training
Hazardous Materials
Bomb Threat
Crossword Puzzles
Biological Agents

Forms & Documents

Forms
Checklists
Audit Guides
Inspections Guides
Signs & Labels
Environmental Audit Guides
Recordkeeping - OSHA 300
Sign & Label Maker

Safety Management Resources

Safety Manuals/Written Programs
Ergonomic Programs
Emergency Plans
Process Safety Management
Construction Safety
Occupational Health
Environmental
Topic Sheets
DOT Fleet-Driver
Hazardous Materials
Chemical Safety
Drug Free Workplace
Terrorism Programs
Development Guides

Safety Manager Software

23 Module Software - Manage, Track, Schedule & OSHA Log
1. Employee Info
2. Accident Reports
3. Incident Reports
4. Lockout - Tagout
5. Corrective Actions
6. Equipment Safety
7. Confined Space
8. Hot Work Permits
9. Vehicle Accidents
10. Safety Committee
11. Industrial Hygiene
12. IR Calculator
13. Respirator Schedule
14. Protective Equipment
15. Chemical Exposure
16. Event Planner
17. Expense Tracker
18. Job Safety Analysis
19. Chemical Data
20. Training Planner
21. Contractors
22. Process Safety
23. Chemical Labels

Safety References & Graphics

Technical Safety Information
Posters
Topic & Fact Sheets
Development Information
Job Specific Safety Rules
Terrorism
Calculators
Safety Comic Strips

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